Integrated Recycling of Lignin-Containing Wood Waste
DOI:
https://doi.org/10.37482/0536-1036-2024-3-188-202Keywords:
wood waste, sawdust, chips, recycling, high-yield pulp, fluting paper, cardboard, paper composition, paper grain quality, sample testingAbstract
The recycling of wood processing waste generated at pulp and paper and woodworking enterprises by reusing it in obtaining a high-yield semi-finished product for the production of paper and cardboard has been studied. The economic and environmental feasibility of wood waste recovery is beyond doubt. The aim has been to develop technology and modes for recycling wood waste from the production of high-yield pulp (birch sawdust) and woodworking (coniferous and the mix of coniferous and deciduous chips). In the course of the study, high-yield pulp has been obtained from birch sawdust using continuous technology (at Perm Pulp and Paper Company) and batch technology (at most pulp and paper industry enterprises). Cooking of wood chips has been carried out only using batch technology. It is shown that the recycling of birch sawdust to produce a fibrous semi-finished product for use in the production of paper and cardboard solves an important economic problem of the pulp and paper industry, which is the need to reduce the consumption of pulpwood and preserve forest resources. The process of recycling wood waste does not require changes to current technology. This produces high-yield pulp, which in terms of quality is not inferior to a similar semi-finished product made from birch technological chips and meets the enterprise standards. It has been revealed that wood chips from coniferous and deciduous wood from woodworking enterprises can also be used as a raw material for the production of high-yield pulp, but only together with sawdust from birch wood. High-yield pulp from the chips of coniferous and the mix of coniferous and deciduous wood is obtained with increased yield, but with low mechanical strength, since the neutral-sulfite method is intended for the production of a fibrous semi-finished product only from deciduous wood; coniferous wood is not boiled using this method. High-yield pulp with quality indicators corresponding to the enterprise standards from technological chips is produced by the ratios of chips and sawdust of 50:50 and 70:30. The yield of the semi-finished product from the raw materials of all used compositions is high – 75…82 %. Tests of high-yield pulp obtained from birch sawdust have shown that the fibrous semi-finished product can replace 20 % of the MS-5B waste paper mass in production in the production of paper and cardboard compositions.
Downloads
References
Альберг Н.И., Санжиева С.Е., Салхофер С. Комплексное устойчивое управление отходами. Деревообрабатывающая и целлюлозно-бумажная промышленность. М.: Акад. естествознания, 2016. 308 с. Al’berg N.I., Sanzhieva S.E., Salkhofer S. Integrated Sustainable Waste Management. Woodworking and Pulp and Paper Industry. Moscow, Academy of Natural History Publ., 2016. 308 p. (In Russ.).
Беловежец Л.А., Волчатова И.В., Медведева С.А. Перспективные способы переработки вторичного лигноцеллюлозного сырья // Химия растит. сырья. 2010. № 2. С. 5–16. Belovezhets L.A., Volchatova I.V., Medvedeva S.A. Promising Methods for Processing Secondary Lignocellulosic Raw Materials. Khimija Rastitel’nogo Syr’ja, 2010, no. 2, pp. 5–16. (In Russ.).
Васильева Т.В. Обзор сложившихся тенденций использования древесных отходов за рубежом // Лесн. вестн. 2002. № 4. С. 71–73. Vasil’yeva T.V. The Review of Current Trends in the Use of Wood Waste Abroad // Lesnoy vestnik = Forestry Bulletin, 2002, no. 4, pp. 71–73. (In Russ.).
Гелес И.С. Древесная биомасса и основы экологически приемлемых технологий ее химико-механической переработки. Петрозаводск: КарНЦ РАН, 2001. 382 с. Geles I.S. Wood Biomass and the Basics of Environment Friendly Technologies for its Chemical and Mechanical Processing. Petrozavodsk, Karelian Research Centre of the Russian Academy of Sciences, 2001. 382 p. (In Russ.).
Гелес И.С. Древесное сырье – стратегическая основа и резерв цивилизации. Петрозаводск: КарНЦ РАН, 2007. 500 с. Geles I.S. Wood Raw Materials – the Strategic Basis and Reserve of Civilization. Petrozavodsk, Karelian Research Centre of the Russian Academy of Sciences, 2007. 500 p. (In Russ.).
Гелес И.С., Коржицкая З.А. Биомасса дерева и ее использование. Петрозаводск, 1992. 201 с. Geles I.S., Korzhitskaya Z.A. Wood Biomass and its Use. Petrozavodsk, 1992. 201 p. (In Russ.).
Ефремов А.А., Первышина Г.Г. Комплексная схема переработки отходов растительного сырья // Химия растит. сырья. 2001. № 4. С. 123–124. Efremov A.A., Pervyshina G.G. Comprehensive Scheme for Processing Waste Plant Materials. Khimija Rastitel’nogo Syr’ja, 2001, no. 4, pp. 123–124. (In Russ.).
Журавлёва Л.Н., Девятловская А.Н. Основные направления использования древесных отходов // Актуал. проблемы лесн. комплекса. 2007. № 18. С. 96–99. Zhuravleva L.N., Devyatlovskaya A.N. The Main Directions of the Use of Wood Waste. Aktual’nye problemy lesnogo kompleksa, 2007, no. 18, pp. 96–99. (In Russ.).
Иванов И.С. Развитие инновационных экотехнологий, базирующихся на использовании древесных отходов // Экономика и управление. 2009. № 12(50). С. 64–69. Ivanov I.S. Development of Innovative Eco-Technologies Based on the Use of Wood Waste. Ekonomika i upravlenie = Economics and Management, 2009, no. 12, pp. 64–69. (In Russ.).
Ковернинский И.Н., Комаров В.И., Третьяков С.И., Богданович Н.И., Соколов О.М., Кутакова Н.А., Селянина Л.И. Комплексная химическая переработка древесины / под ред. проф. И.Н. Ковернинского. Архангельск: АГТУ, 2003. 347 с. Koverninskiy I.N., Komarov V.I., Tret’yakov S.I., Bogdanovich N.I., Sokolov O.M., Kutakova N.A., Selyanina L.I. Complex Chemical Processing of Wood. Ed. by prof. I.N. Koverninskiy. Arkhangelsk, ASTU Publ., 2003. 347 p. (In Russ.).
Кузнецова С.А., Яценкова О.В., Данилов В.Г., Кузнецов Б.Н. Окислительная делигнификация древесины лиственницы в среде уксусная кислота – пероксид водорода – вода в присутствии катализатора Н2МоО4 // Химия растит. сырья. 2005. № 4. С. 35–39. Kuznetsova S.A., Yatsenkova O.V., Danilov V.G., Kuznetsov B.N. Oxidative Delignification of Larch Wood in the Acetic Acid – Hydrogen Peroxide – Water Medium in the Presence of H2MoO4 Catalyst. Khimija Rastitel’nogo Syr’ja, 2005, no. 4, pp. 35–39. (In Russ.).
Патент № 2721503 РФ, МПК D21C 3/00. Способ получения полуцеллюлозы: № 2018140804: заявл. 19.11.2018: опубл. 19.05.2020 / Ф.Х. Хакимова, О.А. Носкова, Е.А. Глезман, В.А. Житнюк, М.Н. Спасенников; заявитель и патентообладатель Перм. нац. исслед. политехн. ун-т. Khakimova F.Kh., Noskova O.A., Glezman E.A., Zhitnyuk V.A., Spasennikov M.N. Method for Producing Semi-Cellulose. Patent RF, no. RU 2721503, 2018. (In Russ.).
Пен Р.З., Бывшев А.В., Шапиро И.Л., Мирошниченко И.В., Тарабанько В.Е. Низкотемпературная окислительная делигнификация древесины. 8. Пероксидная варка и щелочная экстракция // Химия растит. сырья. 2001. № 3. С. 5–10. Pen R.Z., Byvshev A.V., Shapiro I.L., Miroshnichenko I.V., Taraban’ko V.E. Low-Temperature Oxidative Delignification of Wood. 8. Peroxide Pulping and Alkaline Extraction. Khimija Rastitel’nogo Syr’ja, 2001, no. 3, pp. 5–10. (In Russ.).
Пен Р.З., Бывшев А.В., Шапиро И.Л., Мирошниченко И.В., Тарабанько В.Е. Низкотемпературная окислительная делигнификация древесины. 9. Пероксидная варка древесины разных пород // Химия растит. сырья. 2001. № 3. С. 11–15. Pen R.Z., ByvshevA.V., Shapiro I.L., Miroshnichenko I.V., Taraban’ko V.E. Low-Temperature Oxidative Delignification of Wood. 9. Peroxide Pulping of Different Wood Species. Khimija Rastitel’nogo Syr’ja, 2001, no. 3, pp. 11–15. (In Russ.).
Пен Р.З., Рязанова Т.В. Комплексная химическая переработка древесины. Введение в специальность. Красноярск: СибГТУ, 2012. 158 с. Pen R.Z., Ryazanova T.V. Complex Chemical Processing of Wood. Introduction to the Specialty. Krasnoyarsk, SibSTU Publ., 2012. 158 p. (In Russ.).
Полютов А.А., Пен Р.З., Бывшев А.В. Технология целлюлозы. Экологически чистое производство: моногр. Красноярск: Краснояр. писатель, 2012. 294 с. Polyutov A.A., Pen R.Z., Byvshev A.V. Cellulose Technology. Environmentally Friendly Production: Monograph. Krasnoyarsk, Krasnoyarski Pisatel Publ., 2012. 294 p. (In Russ.).
Сафин Р.Г., Саттарова З.Г., Хабибуллин И.Г., Зиатдинов Р.Р., Степанова Т.О. Современные направления переработки лесных ресурсов // Вестн. технол. ун-та. 2015. Т. 18, № 21. С. 90–93. Safin R.G., Sattarova Z.G., Khabibullin I.G., Ziatdinov R.R., Stepanova T.O. Modern Trends in Forest Resources Processing. Vestnik tekhnologicheskogo universiteta = Herald of Technological University, 2015, vol. 18, no. 21, pp. 90–93. (In Russ.).
Технология целлюлозно-бумажного производства: справ. материалы: в 3 т. Т. III. Автоматизация, стандартизация, экономика и охрана окружающей среды в ЦБП. Ч. 3. Наилучшие доступные технологии в целлюлозно-бумажной промышленности. СПб.: Политехника, 2012. 294 с. Technology of Pulp and Paper Production: Reference Materials: in 3 vols. Vol. III. Automation, Standardization, Economics and Environmental Protection in Pulp and Paper Production. Part 3. Best Available Technologies in the Pulp and Paper Industry. St. Petersburg, Politekhnika Publ., 2012. 294 p. (In Russ.).
Фирсов А.И. Использование древесных отходов при очистке лесохимических стоков // Изв. вузов. Лесн. журн. 2003. № 2-3. С. 116–123. Firsov A.I. Use of Wood Wastes for Treatment of Effluents of Forest-Chemical Industry. Lesnoy Zhurnal = Russian Forestry Journal, 2003, no. 2-3, pp. 116–123. (In Russ.).
Хакимов Р.Х., Хакимова Ф.Х., Ковтун Т.Н. Применение аэродинамического диспергатора при подготовке макулатуры для использования в композициях бумаги и картона // Изв. вузов. Лесн. журн. 2013. № 3. С. 121–128. Khakimov R.Kh., Khakimova F.Kh., Kovtun T.N. Preparing of Wastepaper by Aerodynamic Disintegrator for Using in Paper and Board Composition. Lesnoy Zhurnal = Russian Forestry Journal, 2013, no. 3, pp. 121–128. (In Russ.).
Хакимова Ф.Х., Носкова О.А. Отходы лесозаготовок – сырье для волокнистых полуфабрикатов производства картона // Вестн. ПНИПУ. Хим. технология и биотехнология. 2017. № 3. С. 128–143. Khakimova F.Kh., Noskova O.A. Waste from Logging of Trees as a Raw Material for Fibrous Semi-Finished Products for Cardboard Production. Vestnik Permskogo natsional’nogo issledovatel’skogo politekhnicheskogo universiteta. Khimicheskaya tekhnologiya i biotekhnologiya = Vestnik of Perm National Research Polytechnic University. Chemical Technology and Biotechnology, 2017, no. 3, pp. 128–143. (In Russ.). https://doi.org/10.15593/2224-9400/2017.3.11
Хакимова Ф.Х., Носкова О.А., Шевелева С.А., Хакимов Р.Р. Утилизация отходов лесозаготовок с получением полуфабриката для картона // Вестн. ПНИПУ. Приклад. экология. Урбанистика. 2018. № 2(30). С. 60–73. Khakimova F.Kh., Noskova O.A., Sheveleva S.A., Khakimov R.R. Recycling of Logging Waste to Produce Semi-Finished Material for Cardboard. Vestnik Permskogo natsional’nogo issledovatel’skogo politekhnicheskogo universiteta. Priklandaya ekologiya. Urbanistika = Vestnik of Perm National Research Polytechnic University. Applied Ecology. Urbanistics, 2018, no. 2, pp. 60–73. (In Russ.). https://doi.org/10.15593/2409-5125/2018.02.05
Abu Bakar N.H., Salim N. Challenges and Opportunities in Wood Waste Utilization. Wood Waste Management and Products. Sustainable Materials and Technology. Singapore, Springer, 2023, chapt. 1, pp. 1–13. https://doi.org/10.1007/978-981-99-1905-5_1
Ämmälä A., Laitinen O., Sirviö J.A., Liimatainen H. Key Role of Mild Sulfonation of Pine Sawdust in the Production of Lignin Containing Microfibrillated Cellulose by Ultrafine Wet Grinding. Industrial Crops & Products, 2019, vol. 140, art. no. 111664. https://doi.org/10.1016/j.indcrop.2019.111664
Olszewski A., Kosmela P., Piszczyk Ł. A Novel Approach in Wood Waste Utilization for Manufacturing of Catalyst-Free Polyurethane-Wood Composites (PU-WC). Sustainable Materials and Technologies, 2023, vol. 36, art. no. e00619. https://doi.org/10.1016/j.susmat.2023.e00619
Olaiya B.C., Lawan M.M., Olonade K.A. Utilization of Sawdust Composites in Construction = a Review. Discover Applied Sciences, 2023, vol. 5, art. no. 140. https://doi.org/10.1007/s42452-023-05361-4
Sirviö J.A., Isokoski E., Kantola A.M., Komulaimen S., Ämmälä A. Mechanochemical and Thermal Succinylation of Softwood Sawdust in Presence of Deep Eutectic Solvent to Produce Lignin-Containing Wood Nanofibers. Cellulose, 2021, vol. 28, pp. 6681–6898. https://doi.org/10.1007/s10570-021-03973-w
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2024 Ф.Х. Хакимова, О.А. Носкова, Р.Р. Хакимов, И.И. Фонарёв (Автор)
This work is licensed under a Creative Commons Attribution 4.0 International License.
